James Gurney has just published the best explanation of the properties of black that I have ever seen. He has done a four part examination of its use as a pigment, in composition, and properties as a color...or not.  This last installment was my favorite.  As it turns out, it depends on the context of the discussion, and its relation to other colors.  This man is a heck of an educator! 
If you don't read his blog yet, I highly recommend it.  GurneyJourney.blogspot.com
 
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